Publication:
Effect of ionic conductivity of a PAN-PC-LiClO 4 solid polymeric electrolyte on the performance of a TiO 2 photoelectrochemical cell

Simple item page
dc.citedby7
dc.contributor.authorRikaen_US
dc.contributor.authorRahman M.Y.A.en_US
dc.contributor.authorSalleh M.M.en_US
dc.contributor.authorUmar A.A.en_US
dc.contributor.authorAhmad A.en_US
dc.contributor.authorid36009299200en_US
dc.contributor.authorid55347217400en_US
dc.contributor.authorid55613229960en_US
dc.contributor.authorid9332520900en_US
dc.contributor.authorid16306307100en_US
dc.date.accessioned2023-12-29T07:49:24Z
dc.date.available2023-12-29T07:49:24Z
dc.date.issued2010
dc.description.abstractA nanoparticle TiO 2 solid-state photoelectrochemical cell has been fabricated. The effect of ionic conductivity of a solid electrolyte of polyacrylonitrile (PAN)-propylene carbonate (PC)-lithium perchlorate (LiClO 4) on the performance of a photoelectrochemical cell of indium tin oxide (ITO)/TiO 2/PAN-PC-LiClO 4/graphite has been investigated. A nanoparticle TiO 2 film was deposited onto ITO-covered glass substrate by controlled hydrolysis technique. A solid electrolyte of PAN-LiClO 4 with PC plasticizer prepared by solution casting technique was used as a redox couple medium. The room temperature conductivity of the electrolyte was determined by AC impedance spectroscopy technique. A graphite electrode was prepared onto a glass slide by electron beam evaporation technique. The device shows a photovoltaic effect under illumination. The short-circuit current density, J sc, and open-circuit voltage, V oc, vary with the conductivity of the electrolyte. The highest J sc of 2.82 ?A cm -2 and V oc of 0.56 V were obtained at the conductivity of 4.2�10 -4?Scm -1 and at the intensity of 100 mW cm -2. � 2010 Springer-Verlag.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.1007/s10008-010-1040-x
dc.identifier.epage2093
dc.identifier.issue11
dc.identifier.scopus2-s2.0-77956393724
dc.identifier.spage2089
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-77956393724&doi=10.1007%2fs10008-010-1040-x&partnerID=40&md5=52d07de596641dcd711aebf73200f15c
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/30555
dc.identifier.volume14
dc.pagecount4
dc.sourceScopus
dc.sourcetitleJournal of Solid State Electrochemistry
dc.subjectHydrolysis technique
dc.subjectIonic conductivity
dc.subjectNanoparticle titanium dioxide
dc.subjectPAN-PC-LiClO <sub>4</sub>
dc.subjectPhotoelectrochemical cell
dc.subjectElectrochemical electrodes
dc.subjectElectron beams
dc.subjectGraphite
dc.subjectGraphite electrodes
dc.subjectHydrolysis
dc.subjectIndium compounds
dc.subjectIonic conductivity
dc.subjectIons
dc.subjectITO glass
dc.subjectLithium
dc.subjectNanoparticles
dc.subjectOpen circuit voltage
dc.subjectPhotoelectrochemical cells
dc.subjectPlasticizers
dc.subjectPropylene
dc.subjectSolid electrolytes
dc.subjectSubstrates
dc.subjectSwitching circuits
dc.subjectTin
dc.subjectTin oxides
dc.subjectTitanium
dc.subjectTitanium castings
dc.subjectTitanium compounds
dc.subjectTitanium dioxide
dc.subjectAc impedance spectroscopy
dc.subjectControlled hydrolysis
dc.subjectElectron beam evaporation
dc.subjectGlass slides
dc.subjectGlass substrates
dc.subjectIndium tin oxide
dc.subjectLithium perchlorate
dc.subject
dc.subjectPhotoelectrochemicals
dc.subjectPropylene carbonate
dc.subjectRedox couple
dc.subjectRoom-temperature conductivity
dc.subjectSolid polymeric electrolytes
dc.subjectSolution-casting technique
dc.subjectTiO
dc.subjectIonic conduction in solids
dc.titleEffect of ionic conductivity of a PAN-PC-LiClO 4 solid polymeric electrolyte on the performance of a TiO 2 photoelectrochemical cellen_US
dc.typeConference paperen_US
dspace.entity.typePublication
Files
Collections
SCOPUS