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Preparation and characterization of solid polymeric electrolyte of poly(vinyl) chloride-low-molecular weight LENR50 (70/30)-LiClO 4

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dc.citedby6
dc.contributor.authorLee T.K.en_US
dc.contributor.authorAhmad A.en_US
dc.contributor.authorFarina Y.en_US
dc.contributor.authorDahlan H.M.en_US
dc.contributor.authorRahman M.Y.A.en_US
dc.contributor.authorid8610515400en_US
dc.contributor.authorid16306307100en_US
dc.contributor.authorid6505878972en_US
dc.contributor.authorid6508121460en_US
dc.contributor.authorid55347217400en_US
dc.date.accessioned2023-12-29T07:46:48Z
dc.date.available2023-12-29T07:46:48Z
dc.date.issued2012
dc.description.abstractThis work presents the preparation of a free standing electrolyte film containing poly(vinyl) chloride (PVC) and 50% liquid epoxidized natural rubber (LENR50) blends as a host for the electrolyte that was doped with lithium perchlorate (LiClO 4) as the dopant salt. The electrolyte was prepared via solution-casting technique. From the impedance result, the highest ionic conductivity obtained was 9.6 � 10 -9 S cm -1 at the 30 wt % of LiClO 4. This ionic conductivity result was supported by XRD analysis that showed the addition of 5-30 wt % of LiClO 4 salt to the PVC-LENR50 was well dissociated in the electrolyte as no salt peaks were observed. This implies that the salt was fully complexed in the system. Thermal analysis revealed that T g increased with lithium salts concentration. This is due to the formation of transient crosslinkage bonds and increasing viscosity. The morphological studies revealed the good homogeneity of the PVC-LENR50 (70/30) blend as no phase separation was observed. In addition, the formation of micropores with an addition of salts in the electrolyte improved the mobility properties of Li + ions in the electrolyte system. Hence, it improves the ionic conductivity. � 2012 Wiley Periodicals, Inc.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.1002/app.36729
dc.identifier.epageE165
dc.identifier.issueSUPPL. 2
dc.identifier.scopus2-s2.0-84864715722
dc.identifier.spageE159
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84864715722&doi=10.1002%2fapp.36729&partnerID=40&md5=03e418d383ed7210d1b222d41620c58c
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/30333
dc.identifier.volume126
dc.pagecount6
dc.relation.ispartofAll Open Access; Bronze Open Access
dc.sourceScopus
dc.sourcetitleJournal of Applied Polymer Science
dc.subjectionic conductivity
dc.subjectLENR50
dc.subjectLiClO <sub>4</sub>
dc.subjectpolymer electrolyte
dc.subjectPVC
dc.subjectChlorine compounds
dc.subjectFilm preparation
dc.subjectInorganic compounds
dc.subjectIonic conductivity
dc.subjectLithium
dc.subjectPhase separation
dc.subjectPolymers
dc.subjectPolymethyl methacrylates
dc.subjectPolyvinyl chlorides
dc.subjectSalts
dc.subjectThermoanalysis
dc.subjectCross-linkage
dc.subjectDopant salt
dc.subjectElectrolyte films
dc.subjectElectrolyte systems
dc.subjectEpoxidized natural rubber
dc.subjectIncreasing viscosity
dc.subjectLENR50
dc.subject
dc.subjectLithium perchlorate
dc.subjectLithium salts
dc.subjectMicropores
dc.subjectMobility properties
dc.subjectMorphological study
dc.subjectPolymer electrolyte
dc.subjectSolid polymeric electrolytes
dc.subjectSolution-casting technique
dc.subjectXRD analysis
dc.subjectElectrolytes
dc.titlePreparation and characterization of solid polymeric electrolyte of poly(vinyl) chloride-low-molecular weight LENR50 (70/30)-LiClO 4en_US
dc.typeArticleen_US
dspace.entity.typePublication
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