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Nanohardness Properties of MOF-199 Synthesized Using Facile Method as Bulk Adsorbents and Screen-Printed Thin-Film

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dc.contributor.authorFadli M.F.M.en_US
dc.contributor.authorOthman S.Z.en_US
dc.contributor.authorWai O.J.en_US
dc.contributor.authorAmin N.en_US
dc.contributor.authorMatsumoto A.en_US
dc.contributor.authorMisran H.en_US
dc.contributor.authorid57411757600en_US
dc.contributor.authorid55548997100en_US
dc.contributor.authorid57485940500en_US
dc.contributor.authorid7102424614en_US
dc.contributor.authorid14525231700en_US
dc.contributor.authorid6506899840en_US
dc.date.accessioned2023-05-29T09:41:25Z
dc.date.available2023-05-29T09:41:25Z
dc.date.issued2022
dc.descriptionActivated carbon; Crystal structure; Crystalline materials; Crystallinity; Glass substrates; Hybrid materials; Morphology; Organometallics; Screen printing; Thin films; Zeolites; Binderless; Facile method; Fatty alcohols; MOF-199; Oil based; Property; Reduced modulus; Screen-printed; Synthesised; Thin-films; Fabricationen_US
dc.description.abstractThis paper reports on the nanohardness properties of copper-based metal-organic framework (MOF-199) synthesized in-house by facile method fabricated into bulk adsorbents by binder-less compression and into thin-film by screen-printing. 13�mm diameter bulk adsorbents were prepared for four different materials 1) MOF-199, 2) zeolite 13X, 3) activated carbon (AC) and 4) hybrid MOF-199: AC (1:1). In addition, MOF-199 was fabricated into thin-film on soda-lime glass substrates using screen-printing method. Polyvinyl acetate (PVA) was replaced with environmental-friendly binder materials of gum Arabic (gA) and palm oil based fatty alcohol (PODFA) with 8 carbon chain of decyl alcohol. X-ray diffraction (XRD) analyses of MOF-199 fabricated both by binder-less compression and screen-printing exhibited a prominent peak at ca. 2? = 11.7� attributable to (222) reflection plane of octahedral crystal structure suggesting that morphology and crystallinity were retained after fabrication processes. The octahedral morphology at ca. 1��m and ca. 2��m were observed for screen-printed thin film suggesting that the structure was preserved. Reduced modulus (R*) for pure MOF-199 and hybrid MOF-199:AC bulk adsorbents were at ca. 2.818�GPa and 0.002�GPa, respectively suggesting that hybrid adsorbent was not suitable for applications due to lack of hardness. Reduced modulus value of MOF-199 thin-film were higher at ca. 6.577�GPa (gA), 3.539�GPa (PVA), and 0.816�GPa (PODFA), respectively. � 2022, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.1007/978-981-16-9949-8_15
dc.identifier.epage85
dc.identifier.scopus2-s2.0-85126228229
dc.identifier.spage80
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85126228229&doi=10.1007%2f978-981-16-9949-8_15&partnerID=40&md5=076e60c943b3a4a88424dd10a888bb35
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/27239
dc.publisherSpringer Science and Business Media Deutschland GmbHen_US
dc.sourceScopus
dc.sourcetitleLecture Notes in Mechanical Engineering
dc.titleNanohardness Properties of MOF-199 Synthesized Using Facile Method as Bulk Adsorbents and Screen-Printed Thin-Filmen_US
dc.typeConference Paperen_US
dspace.entity.typePublication
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