Publication:
Effect of ethylene carbonate plasticizer and TiO2 nanoparticles on 49% poly(methyl methacrylate) grafted natural rubber-based polymer electrolyte

Simple item page
dc.citedby28
dc.contributor.authorLow S.P.en_US
dc.contributor.authorAhmad A.en_US
dc.contributor.authorRahman M.Y.A.en_US
dc.contributor.authorid36448840400en_US
dc.contributor.authorid16306307100en_US
dc.contributor.authorid55347217400en_US
dc.date.accessioned2023-12-29T07:50:39Z
dc.date.available2023-12-29T07:50:39Z
dc.date.issued2010
dc.description.abstractThe effect of plasticizer and TiO2 nanoparticles on the conductivity, chemical interaction and surface morphology of polymer electrolyte of MG49-EC-LiClO4-TiO2 has been investigated. The electrolyte films were successfully prepared by solution casting technique. The ceramic filler, TiO2, was synthesized in situ by sol-gel process and was added into the MG49-EC-LiClO4 electrolyte system. Alternating current electrochemical impedance spectroscopy was employed to investigate the ionic conductivity of the electrolyte films at 25 �C, and the analysis showed that the addition of TiO2 filler and ethylene carbonate (EC) plasticizer has increased the ionic conductivity of the electrolyte up to its optimum level. The highest conductivity of 1.1 � 10-3 Scm-1 was obtained at 30 wt.% of EC. Fourier transform infrared spectroscopy measurement was employed to study the interactions between lithium ions and oxygen atoms that occurred at carbonyl (C=O) and ether (C-O-C) groups. The scanning electron microscopy micrograph shows that the electrolyte with 30 wt.% EC posses the smoothest surface for which the highest conductivity was obtained. � 2010 Springer-Verlag.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.1007/s11581-010-0470-x
dc.identifier.epage826
dc.identifier.issue9
dc.identifier.scopus2-s2.0-78649664187
dc.identifier.spage821
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-78649664187&doi=10.1007%2fs11581-010-0470-x&partnerID=40&md5=f6b2f0220eeaea0510ab6bd79aa4d23f
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/30637
dc.identifier.volume16
dc.pagecount5
dc.sourceScopus
dc.sourcetitleIonics
dc.subject49% Poly(methyl methacrylate) grafted natural rubber (MG49)
dc.subjectConductivity
dc.subjectEthylene carbonate
dc.subjectInfrared
dc.subjectTiO<sub>2</sub>
dc.subjectAtomic spectroscopy
dc.subjectCarbonation
dc.subjectElectrochemical corrosion
dc.subjectEsters
dc.subjectEthers
dc.subjectEthylene
dc.subjectFillers
dc.subjectFourier transform infrared spectroscopy
dc.subjectFourier transforms
dc.subjectGrafting (chemical)
dc.subjectIonic conductivity
dc.subjectIons
dc.subjectLithium
dc.subjectNanoparticles
dc.subjectOxygen
dc.subjectPlasticizers
dc.subjectPolyelectrolytes
dc.subjectReinforced plastics
dc.subjectRubber
dc.subjectScanning electron microscopy
dc.subjectSol-gel process
dc.subjectConductivity
dc.subjectEthylene carbonate
dc.subjectInfrared
dc.subjectNatural Rubber
dc.subjectTiO
dc.subjectElectrochemical impedance spectroscopy
dc.titleEffect of ethylene carbonate plasticizer and TiO2 nanoparticles on 49% poly(methyl methacrylate) grafted natural rubber-based polymer electrolyteen_US
dc.typeArticleen_US
dspace.entity.typePublication
Files
Collections
SCOPUS