Publication: Fabricating of multi-interfacial charge transfer paths in the novel noble-metal-free Ni2P/ZnS/g-C3N4 ternary nanocomposite for enhanced charge separation and transfer for photocatalytic H2 generation
| dc.citedby | 1 | |
| dc.contributor.author | Rameshbabu R. | en_US |
| dc.contributor.author | Paw J.K.S. | en_US |
| dc.contributor.author | Ajaijawahar K. | en_US |
| dc.contributor.author | Vinoth V. | en_US |
| dc.contributor.author | Jadoun S. | en_US |
| dc.contributor.author | Pugazhenthiran N. | en_US |
| dc.contributor.author | Kiong T.S. | en_US |
| dc.contributor.authorid | 55621066400 | en_US |
| dc.contributor.authorid | 58168727000 | en_US |
| dc.contributor.authorid | 57218329653 | en_US |
| dc.contributor.authorid | 56662096500 | en_US |
| dc.contributor.authorid | 57189469761 | en_US |
| dc.contributor.authorid | 23989733500 | en_US |
| dc.contributor.authorid | 57216824752 | en_US |
| dc.date.accessioned | 2025-03-03T07:42:35Z | |
| dc.date.available | 2025-03-03T07:42:35Z | |
| dc.date.issued | 2024 | |
| dc.description.abstract | This work reports the development of a novel Ni?P/ZnS/C?N? ternary nanocomposite photocatalyst for efficient hydrogen (H?) production. The nanocomposite was synthesized using a facile approach combining hydrothermal synthesis, ball milling, and wet impregnation methods then characterized using various techniques. Photocatalytic H? generation was evaluated under simulated solar irradiation with sodium sulfite (Na?SO?)/sodium sulfide (Na?S) as sacrificial reagents. The optimized 3NP/ZnS-8CN (3% Ni2P/ZnS/8% C3N4) catalyst displayed an exceptional H? generation rate of 3991 �mol h?? g??, exceeding both pristine g-C3N4 (by 10.2 times) and 3% Ni2P/ZnS (by 1.2 times). This represents the highest reported rate of H? evolution for a graphitic carbon nitride (g-C3N4) based ternary nanocomposite under simulated solar radiation. Furthermore, the 3NP/ZnS-8CN photocatalyst exhibited good stability over four reaction cycles. This study provides valuable insights for designing efficient noble metal-free g-C3N4-based photocatalysts, which can significantly contribute to the transition to solar-driven hydrogen generation. The results of this study suggest that the synthesized composite materials hold significant promise for the advancement of new energy technologies. ? 2024 Elsevier B.V. | en_US |
| dc.description.nature | Final | en_US |
| dc.identifier.ArtNo | 174830 | |
| dc.identifier.doi | 10.1016/j.jallcom.2024.174830 | |
| dc.identifier.scopus | 2-s2.0-85193497458 | |
| dc.identifier.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85193497458&doi=10.1016%2fj.jallcom.2024.174830&partnerID=40&md5=28767af4b10c7a7672e009128ea59aed | |
| dc.identifier.uri | https://irepository.uniten.edu.my/handle/123456789/36469 | |
| dc.identifier.volume | 997 | |
| dc.publisher | Elsevier Ltd | en_US |
| dc.source | Scopus | |
| dc.sourcetitle | Journal of Alloys and Compounds | |
| dc.subject | Ball milling | |
| dc.subject | Carbon nitride | |
| dc.subject | Charge transfer | |
| dc.subject | Hydrogen production | |
| dc.subject | Hydrothermal synthesis | |
| dc.subject | Nanocomposites | |
| dc.subject | Photocatalytic activity | |
| dc.subject | Precious metals | |
| dc.subject | Solar light | |
| dc.subject | Solar power generation | |
| dc.subject | Carrier transfer | |
| dc.subject | Co-catalyse | |
| dc.subject | Energy | |
| dc.subject | H 2 production | |
| dc.subject | Interfacial charge transfer | |
| dc.subject | Metal free | |
| dc.subject | Ni2P/ZnS/g-C3N4 | |
| dc.subject | Photo-catalytic | |
| dc.subject | Synthesised | |
| dc.subject | Ternary nanocomposites | |
| dc.subject | Sulfur compounds | |
| dc.title | Fabricating of multi-interfacial charge transfer paths in the novel noble-metal-free Ni2P/ZnS/g-C3N4 ternary nanocomposite for enhanced charge separation and transfer for photocatalytic H2 generation | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |