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Effect of ZnO nanoparticles filler concentration on the properties of PEO-ENR50-LiCF3SO3 solid polymeric electrolyte

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dc.citedby31
dc.contributor.authorNoor S.A.M.en_US
dc.contributor.authorAhmad A.en_US
dc.contributor.authorTalib I.A.en_US
dc.contributor.authorRahman M.Y.A.en_US
dc.contributor.authorid35386952000en_US
dc.contributor.authorid16306307100en_US
dc.contributor.authorid7801465202en_US
dc.contributor.authorid55347217400en_US
dc.date.accessioned2023-12-29T07:48:24Z
dc.date.available2023-12-29T07:48:24Z
dc.date.issued2011
dc.description.abstractA solid polymer electrolyte comprising blend of poly(ethylene oxide) and 50% epoxidized natural rubber (ENR50) as a polymer host, LiCF3SO3 as a salt and nanoparticle ZnO as an inorganic filler was prepared by solution-casting technique. The effect of filler on the electrolyte properties was characterized and analysed. FESEM analysis showed that the filler was well distributed in the polymer matrix, while the effective interaction between the salt and the polymer host was reduced by the addition of filler. As evidenced by FTIR analysis, which showed the formation of triplet peak at C-O-C stretching region. Ionic conductivity was found to decrease from 1. 4 � 10-4 Scm-1 to 2. 5 � 10-6 Scm-1 upon the addition of filler, due to the blocking effect of filler into the electrolyte conduction pathways. The temperature dependence on the electrolyte conductivity obeys Arrhenius rule in two temperature regions. � 2011 Springer-Verlag.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.1007/s11581-011-0534-6
dc.identifier.epage456
dc.identifier.issue5
dc.identifier.scopus2-s2.0-79957856785
dc.identifier.spage451
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-79957856785&doi=10.1007%2fs11581-011-0534-6&partnerID=40&md5=f89dd6877d4765230fbb5165ad10303e
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/30488
dc.identifier.volume17
dc.pagecount5
dc.sourceScopus
dc.sourcetitleIonics
dc.subjectArrhenius behaviour
dc.subjectIonic conductivity
dc.subjectPoly(ethylene oxide) (PEO)-50% epoxidised natural rubber (ENR50)
dc.subjectZnO nanoparticle filler
dc.subjectEthylene
dc.subjectFillers
dc.subjectIonic conduction
dc.subjectIonic conductivity
dc.subjectNanoparticles
dc.subjectPolyelectrolytes
dc.subjectPolyethylene oxides
dc.subjectRubber
dc.subjectZinc oxide
dc.subjectArrhenius
dc.subjectBlocking effect
dc.subjectEffective interactions
dc.subjectElectrolyte conduction
dc.subjectElectrolyte conductivity
dc.subjectElectrolyte properties
dc.subjectEpoxidized natural rubber
dc.subjectFiller concentration
dc.subjectFTIR analysis
dc.subjectInorganic fillers
dc.subjectPoly(ethylene oxide) (PEO)-50% epoxidised natural rubber (ENR50)
dc.subjectSolid polymer electrolytes
dc.subjectSolid polymeric electrolytes
dc.subjectSolution-casting technique
dc.subjectStretching region
dc.subjectTemperature dependence
dc.subjectTwo-temperature
dc.subjectZnO
dc.subjectZnO nanoparticles
dc.subjectFilled polymers
dc.titleEffect of ZnO nanoparticles filler concentration on the properties of PEO-ENR50-LiCF3SO3 solid polymeric electrolyteen_US
dc.typeArticleen_US
dspace.entity.typePublication
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