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Synthesis, spectral and magnetic studies of newly mixed-ligand complexes of 4-Formyl-Acetanilide Thiosemicarbazone and 3,4-dihydrocinnamic acid with some metal ions

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dc.citedby3
dc.contributor.authorShaker S.A.en_US
dc.contributor.authorid31767661500en_US
dc.date.accessioned2023-12-29T07:50:46Z
dc.date.available2023-12-29T07:50:46Z
dc.date.issued2010
dc.description.abstractNew complexes with thiosemicarbazone derivative and 3, 4-dihydrocinnamic acid were prepared and characterized by elemental analysis, determination of metal, IR, 1H NMR, electronic spectroscopy and magnetic measurements. The thiosemicarbazone derivative forms bidentate ligand complexes of the general formula, [M(Thz)(Caf)] where Thz = 4-formylacetanilide thiosemicarbazone, Caf = 3,4-dihydrocinnamic acid and M=Mn2+, Fe 2+, Co2+, Ni2+, Cu2+, Zn 2+, Cd2+ and Pb2+. The IR and 1H NMR spectra indicates that the (Thz) was coordinated with the metal ions through the N and S atoms and the (Caf) was negatively charged bidentat ligand and was coordinated with the metal ions through the two O atoms. Electronic spectra and magnetic susceptibility measurements of the solid complexes indicates the tetrahedral geometry around the Mn2+, Fe2+, Co 2+, Ni2+, Zn2+, Cd2+ and irregular tetrahedral geometry around Pb2+ ion while the Cu2+ complex has squar planer geometry.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.1155/2010/307842
dc.identifier.epageS600
dc.identifier.issueSUPPL. 1
dc.identifier.scopus2-s2.0-79953077532
dc.identifier.spageS594
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-79953077532&doi=10.1155%2f2010%2f307842&partnerID=40&md5=14515484ffbc40d7b9b0e16631edebd0
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/30645
dc.identifier.volume7
dc.pagecount6
dc.publisherHindawi Limiteden_US
dc.relation.ispartofAll Open Access; Gold Open Access; Green Open Access
dc.sourceScopus
dc.sourcetitleE-Journal of Chemistry
dc.subject3,4-Dihydrocinnamic acid complexes
dc.subject4-Formyl-acetanilide thiosemicarbazone complexes
dc.subjectCaffeic acid complexes
dc.subjectMixed-ligand complexes
dc.titleSynthesis, spectral and magnetic studies of newly mixed-ligand complexes of 4-Formyl-Acetanilide Thiosemicarbazone and 3,4-dihydrocinnamic acid with some metal ionsen_US
dc.typeArticleen_US
dspace.entity.typePublication
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