Publication:
Nonsurfactant synthesis and characterizations of metal-organic framework MOF-5 materials using fatty alcohols

Simple item page
dc.citedby6
dc.contributor.authorMisran H.en_US
dc.contributor.authorOthman S.Z.en_US
dc.contributor.authorManap A.en_US
dc.contributor.authorPauzi N.I.M.en_US
dc.contributor.authorRamesh S.en_US
dc.contributor.authorid6506899840en_US
dc.contributor.authorid55548997100en_US
dc.contributor.authorid57200642155en_US
dc.contributor.authorid26536518100en_US
dc.contributor.authorid41061958200en_US
dc.date.accessioned2023-05-16T02:47:33Z
dc.date.available2023-05-16T02:47:33Z
dc.date.issued2014
dc.description.abstractMetal-organic framework (MOF-5) nano/micro crystals materials with cubic, faceted of truncated octahedron and tetragonal morphology at ca. 0.26 ?m to 3.0 ?m were successfully synthesized using aliphatic (fatty) alcohols based sol-gel method at room temperature without further aging process. Fatty alcohols derived from palm oil with long carbon chain length of 8, 10 and 12 (i.e., octyl alcohol, decyl alcohol and dodecyl alcohol) were used during the synthesis to replace commercial surfactants. Fatty alcohols molecules was suggested to form self-assemblies at the air-water interface by surface-tension auto-oscillations and form pre-polymers that bind to the precursors where upon drying formed porous structure inside the materials. The length of carbon chains in the backbone of fatty alcohol that were used to replace the surfactant during the synthesis affected the structure of resulting MOF-5. Longer carbon chains (i.e., dodecyl alcohol) resulted in more structured framework of metal clusters and linkers with high porosity as compared to shorter template of octyl alcohol and decyl alcohol. © 2014 by American Scientific Publishers.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.1166/sam.2014.1935
dc.identifier.epage1644
dc.identifier.issue7
dc.identifier.scopus2-s2.0-84902977301
dc.identifier.spage1638
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84902977301&doi=10.1166%2fsam.2014.1935&partnerID=40&md5=fff5d669000acffe569db18c4e085633
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/22119
dc.identifier.volume6
dc.publisherAmerican Scientific Publishersen_US
dc.sourceScopus
dc.sourcetitleScience of Advanced Materials
dc.titleNonsurfactant synthesis and characterizations of metal-organic framework MOF-5 materials using fatty alcoholsen_US
dc.typeArticleen_US
dspace.entity.typePublication
Files
Collections
SCOPUS