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Electrical properties of a solid polymeric electrolyte of PVC-ZnO-LiClO4

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dc.citedby18
dc.contributor.authorRahman M.Y.A.en_US
dc.contributor.authorAhmad A.en_US
dc.contributor.authorWahab S.A.en_US
dc.contributor.authorid55347217400en_US
dc.contributor.authorid16306307100en_US
dc.contributor.authorid24377043100en_US
dc.date.accessioned2023-12-29T07:55:28Z
dc.date.available2023-12-29T07:55:28Z
dc.date.issued2009
dc.description.abstractThe ZnO filler has been introduced into a solid polymeric electrolyte of polyvinyl chloride (PVC)-ZnO-LiClO4, replacing costly organic filler for conductivity improvement. Ionic conductivity of PVC-ZnO-LiClO4 as a function of ZnO concentration and temperature has been studied. The electrolyte samples were prepared by solution casting technique. The ionic conductivity was measured using impedance spectroscopy technique. It was observed that the conductivity of the electrolyte varies with ZnO concentration and temperature. The temperature dependence on the conductivity of electrolyte was modelled by Arrhenius and Vogel-Tammann-Fulcher equations, respectively. The temperature dependence on the conductivity does not fit in both models. The highest room temperature conductivity of the electrolyte of 3. 7?�?10-7 Scm-1 was obtained at 20% by weight of ZnO and that without ZnO filler was found to be 8. 8?�?10-10 Scm-1. The conductivity has been improved by 420 times when the ZnO filler was introduced into the PVC-LiClO4 electrolyte system. It was also found that the glass transition temperature of the electrolyte PVC-ZnO-LiClO4 is about the same as PVC-LiClO4. The increase in conductivity of the electrolyte with the ZnO filler was explained in terms of its surface morphology. � 2008 Springer-Verlag.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.1007/s11581-008-0262-8
dc.identifier.epage225
dc.identifier.issue2
dc.identifier.scopus2-s2.0-63949088346
dc.identifier.spage221
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-63949088346&doi=10.1007%2fs11581-008-0262-8&partnerID=40&md5=420bc5a33ac4b719a867dc32a4c8d1da
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/30896
dc.identifier.volume15
dc.pagecount4
dc.sourceScopus
dc.sourcetitleIonics
dc.subjectDifferential scanning calorimetry (DSC)
dc.subjectIonic conductivity
dc.subjectPolymers
dc.subjectScanning electron microscopy (SEM)
dc.subjectChlorine compounds
dc.subjectDifferential scanning calorimetry
dc.subjectElectric properties
dc.subjectElectrolysis
dc.subjectFillers
dc.subjectGlass transition
dc.subjectIonic conductivity
dc.subjectIons
dc.subjectLaser interferometry
dc.subjectPlastic products
dc.subjectPolyelectrolytes
dc.subjectPolymers
dc.subjectPolyvinyl chlorides
dc.subjectScanning
dc.subjectScanning electron microscopy
dc.subjectSemiconducting zinc compounds
dc.subjectTemperature distribution
dc.subjectZinc oxide
dc.subjectArrhenius
dc.subjectConductivity improvements
dc.subjectElectrical properties
dc.subjectElectrolyte systems
dc.subjectGlass transition temperatures
dc.subjectImpedance spectroscopies
dc.subjectOrganic fillers
dc.subjectRoom-temperature conductivities
dc.subjectSolid polymeric electrolytes
dc.subjectSolution-casting techniques
dc.subjectTemperature dependences
dc.subjectVogel-Tammann-Fulcher equations
dc.subjectZno
dc.subjectConducting polymers
dc.titleElectrical properties of a solid polymeric electrolyte of PVC-ZnO-LiClO4en_US
dc.typeArticleen_US
dspace.entity.typePublication
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