Publication: Preparation and study of some Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and pb(II) complexes containing heterocyclic nitrogen donor ligands
| dc.citedby | 6 | |
| dc.contributor.author | Shaker S.A. | en_US |
| dc.contributor.authorid | 31767661500 | en_US |
| dc.date.accessioned | 2023-12-29T07:51:07Z | |
| dc.date.available | 2023-12-29T07:51:07Z | |
| dc.date.issued | 2010 | |
| dc.description.abstract | This paper presents a new mixed-ligand complexes with the general formula [M(BT)(BI)2X2] where BT=benzotriazole, BI=benzimidazole, X=SCN and M=Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II). The reaction was carried out by using the appropriate molar ratios of metal:ligand (1:1:2:2) (M:BT:BI:X) as required. The resulting products were found to be solids, not soluble in water and in ordinary organic solvents but highly soluble in DMSO. These complexes have been studied by UV-Visible, IR and (1H, 13C) NMR spectra, molar conductivity, elemental analysis of C, H, N, determination of metal and magnetic susceptibility. The result suggests that the benzimidazoleas as a monodentate was coordinated with the metal ions through the N atom. Nevertheless, the benzotriazole as bidentate was coordinated with the metal ions through the N2 and N3 atoms. SCN was coordinated with the metal ions through the nitogen atom. | en_US |
| dc.description.nature | Final | en_US |
| dc.identifier.doi | 10.1155/2010/793261 | |
| dc.identifier.epage | 1604 | |
| dc.identifier.issue | 4 | |
| dc.identifier.scopus | 2-s2.0-77957327454 | |
| dc.identifier.spage | 1598 | |
| dc.identifier.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-77957327454&doi=10.1155%2f2010%2f793261&partnerID=40&md5=12885ab59beced6f6a6dd8f9fc2fa20b | |
| dc.identifier.uri | https://irepository.uniten.edu.my/handle/123456789/30670 | |
| dc.identifier.volume | 7 | |
| dc.pagecount | 6 | |
| dc.publisher | Hindawi Limited | en_US |
| dc.relation.ispartof | All Open Access; Gold Open Access; Green Open Access | |
| dc.source | Scopus | |
| dc.sourcetitle | E-Journal of Chemistry | |
| dc.subject | Benzimidazole complexes | |
| dc.subject | Benzotriazole complexes | |
| dc.subject | Heterocyclic nitrogen donor ligands | |
| dc.subject | Mixed ligand complexes | |
| dc.title | Preparation and study of some Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and pb(II) complexes containing heterocyclic nitrogen donor ligands | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication |