Publication:
Structural and optical characterization of As-grown and annealed ZnxCd1-xS thin-films by CBD for solar cell applications

dc.citedby3
dc.contributor.authorAhamed E.M.K.I.en_US
dc.contributor.authorDas N.K.en_US
dc.contributor.authorGupta A.K.S.en_US
dc.contributor.authorKhan M.N.I.en_US
dc.contributor.authorMatin M.A.en_US
dc.contributor.authorAmin N.en_US
dc.contributor.authorid57204121738en_US
dc.contributor.authorid34867805900en_US
dc.contributor.authorid57203811680en_US
dc.contributor.authorid56610978700en_US
dc.contributor.authorid57220488718en_US
dc.contributor.authorid7102424614en_US
dc.date.accessioned2023-05-29T08:12:30Z
dc.date.available2023-05-29T08:12:30Z
dc.date.issued2020
dc.descriptionAbsorption spectroscopy; Annealing; Binary alloys; Buffer layers; Crystallinity; Deposition; Energy gap; Morphology; Optical films; Optical properties; Semiconductor alloys; Structural properties; Surface morphology; Thin film solar cells; X ray diffraction; Zinc; Annealing; As-grown; As-grown films; Chemical-bath deposition; FESEM; Thin-films; UV-vis-NIR; XRD; Zinc content; Znxcd1-xS; Thin filmsen_US
dc.description.abstractWe report the synthesis of ZnxCd1-xS (x=0 to 0.41) thin-films by chemical bath deposition technique and annealing of the as-grown Zn0.31Cd0.69S films at 200�C, 350�C and 500�C. The structural properties, optical properties, surface morphology and elemental composition of the films are characterized by XRD, UV-Vis N.I.R. spectroscopy, EDX. and FESEM. The thickness of the as-grown films is measured by the DEKTAK stylus profilometer and is in the range of ~100 nm-120 nm. The as-grown films show quasi-crystalline nature with preferential orientation along (002) hexagonal plane and the crystallinity is declined with the increment of zinc content. Also, the FESEM micrographs show the homogeneous growth, pinhole-free surface and compactness of the films. The transmission edge is shifted towards the short wavelength region as the relative zinc content increases, which confirms the significant reduction of photon absorption in the blue region of the solar spectrum. The as-grown films show average transmittance of ~80-90% along with a tunable bandgap of 2.50eV to 3.35eV for the variation of relative zinc content from 0 to 0.41. The annealing treatment improves the crystalline properties of Zn0.31Cd0.69S film and the best crystallinity is obtained at 350�C temperature. Meanwhile, the annealed Zn0.31Cd0.69S films also exhibit a variable bandgap of 2.85eV, 3.10eV and 3.22eV at 200�C, 350�C and 500�C respectively whereas the bandgap of the as-grown film is 3.12eV. Annealed Zn0.31Cd0.69S thin-film at 350�C having enhanced structural properties without affecting optical characteristics and therefore it can be suitable as a good alternative buffer layer for thin-film solar cell applications. � 2020 International Journal of Renewable Energy Research.en_US
dc.description.natureFinalen_US
dc.identifier.epage1475
dc.identifier.issue3
dc.identifier.scopus2-s2.0-85092186597
dc.identifier.spage1464
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85092186597&partnerID=40&md5=05a8a7b2373375d5c1d379c9faebf9f3
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/25669
dc.identifier.volume10
dc.publisherInternational Journal of Renewable Energy Researchen_US
dc.sourceScopus
dc.sourcetitleInternational Journal of Renewable Energy Research
dc.titleStructural and optical characterization of As-grown and annealed ZnxCd1-xS thin-films by CBD for solar cell applicationsen_US
dc.typeArticleen_US
dspace.entity.typePublication
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