Publication: Preparation, spectroscopic characterization of a new Cd(II) complex containing tridentate NNO Schiff base derived and X-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene] hydrazone
Date
2012
Authors
Alhadi A.A.
Shaker S.A.
Suleiman N.G.
Yehye W.A.
Ali H.M.
Journal Title
Journal ISSN
Volume Title
Publisher
Sociedad Chilena de Quimica
Abstract
A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure analysis. The elemental analysis, FTIR, UV-Vis, 1H NMR spectral and Thermal analysis indicates that the Schiff base ligand GAPy is a tridentate ligand which is coordinated with the Cd(II) complex through N,N and O atoms. Thus, the acetate ion is a bidentate ligand that is coordinated with the metal ion through two O atoms.
Description
Keywords
Cd(II) complexes , Hydrazone derivatives complexes , Schiff base derivatives , Spectroscopic characterization