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Facile solvothermal synthesis of MIL-53 (Al) using waste consumer PET: structural considerations

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dc.citedby1
dc.contributor.authorAzmin A.N.en_US
dc.contributor.authorMisran H.en_US
dc.contributor.authorid57220123847en_US
dc.contributor.authorid6506899840en_US
dc.date.accessioned2025-03-03T07:42:43Z
dc.date.available2025-03-03T07:42:43Z
dc.date.issued2024
dc.description.abstractA facile solvothermal method was applied to synthesize MIL-53 (Al) at room temperature with an organic linker from waste consumer PET. MIL-53 (Al) was built from Al(NO3)3.9H2O connected by 1,4-benzenedicarboxylate (BDC) linkers. The waste plastic bottle was depolymerized to produce monomer BDC. The structural considerations of MIL-53 (Al) were done by using three different linkers, which are a pure linker, a BDC-PET linker, and a BDC-comm-PET linker. The investigation was obtained at two different aging durations of 24 hours and 48 hours. The X-ray diffraction peaks indicated the crystallization formed at diffraction planes of (110), (011), and (211), and the 48-hour samples observed higher crystallinity. Thermal analysis of samples exhibited weight loss at three stages attributed to the removal of solvent and molecules, trapping BDC, and the departure of BDC to the framework, respectively. Raman shift was obtained to show the MIL-53 (Al) structure while the FTIR spectra exhibited the absorption peaks and stretching vibrations of each group. The primary crystallite size was calculated from the Scherrer equation, and the range was between ca. 10 nm and 32 nm. Furthermore, the value observed using a William-Hall (WH) plot showed the crystallite size was almost similar in the range of ca. 8 nm to 21 nm. The FESEM morphology observed the rod-like structure of MIL-53 (Al), and the 48-hour samples observed the larger particle. ? 2024, Universiti Malaysia Perlis. All rights reserved.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.58915/ijneam.v17i3.1172
dc.identifier.epage478
dc.identifier.issue3
dc.identifier.scopus2-s2.0-85202742589
dc.identifier.spage472
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85202742589&doi=10.58915%2fijneam.v17i3.1172&partnerID=40&md5=86fba1b1249f0b179f815eb36c3ebf0b
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/36498
dc.identifier.volume17
dc.pagecount6
dc.publisherUniversiti Malaysia Perlisen_US
dc.relation.ispartofAll Open Access; Hybrid Gold Open Access
dc.sourceScopus
dc.sourcetitleInternational Journal of Nanoelectronics and Materials
dc.titleFacile solvothermal synthesis of MIL-53 (Al) using waste consumer PET: structural considerationsen_US
dc.typeArticleen_US
dspace.entity.typePublication
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