Publication: Synthesis, magnetic and spectroscopic studies of Ni(II), Cu(II), Zn(II) and Cd(II) complexes of a newly Schiff base derived from 5-bromo-2- hydroxybezylidene)-3,4,5-trihydroxybenzohydrazide)
Date
2012
Authors
Alhadi A.A.
Shaker S.A.
Yehye W.A.
Ali H.M.
Abdullah M.A.
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Abstract
A new hydrazide Shiff base ligand GHL1 (5-bromo-2-hydroxybezylidene)-3,4,5- trihydroxybenzohydrazide) was prepared by refluxing of trihydroxybenzhydrazide with an ethanolic of 5-bromo- 2-hydroxybenzaldehyde. The ligand reacted with Ni(II), Cu(II), Zn(II) and Cd(II) (acetate salts). All the complexes were characterized by elemental analysis, molar conductivity, TGA, UV-Vis and FT-IR spectral studies. All the complexes have octahedral geometry except Ni(II) complex which has tetrahedral geometry. � 2012 Chemical Society of Ethiopia.
Description
Keywords
Hydrazone complexes , Schiff base ligand , Spectral studies