Publication:
Review of Mott-Schottky-Based Nanoscale Catalysts for Electrochemical Water Splitting

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dc.citedby7
dc.contributor.authorKrishnamachari M.en_US
dc.contributor.authorLenus S.en_US
dc.contributor.authorPradeeswari K.en_US
dc.contributor.authorArun pandian R.en_US
dc.contributor.authorKumar M.en_US
dc.contributor.authorChang J.-H.en_US
dc.contributor.authorMuthu S.P.en_US
dc.contributor.authorPerumalsamy R.en_US
dc.contributor.authorDai Z.en_US
dc.contributor.authorVijayakumar P.en_US
dc.contributor.authorid58292418200en_US
dc.contributor.authorid57323078600en_US
dc.contributor.authorid57203965456en_US
dc.contributor.authorid58631244100en_US
dc.contributor.authorid57216133294en_US
dc.contributor.authorid12754164000en_US
dc.contributor.authorid58702968600en_US
dc.contributor.authorid57214406951en_US
dc.contributor.authorid37016057800en_US
dc.contributor.authorid56742208000en_US
dc.date.accessioned2024-10-14T03:17:33Z
dc.date.available2024-10-14T03:17:33Z
dc.date.issued2023
dc.description.abstractFundamental structural modification of nanomaterials perpetually presents a phenomenal technique to control the electronic structure of active sites, thereby improving the electrocatalytic activities. Nevertheless, appropriate surface reconstruction is necessary to overcome the large electrochemical overpotential that remains unexplored. In such scenarios, a deep understanding of fundamental structural modification mechanisms, including the Janus structure, spillover effect, d-band center shift theory, and interfacial coupling, is essential. One such fundamental interface and valence engineering strategy includes the Mott-Schottky (M-S) effect. Recently, M-S heterostructure catalysts have piqued the interest of researchers due to their ability to enable mass transport, regulate the density of states, enable continuous rapid electron transfer via band bending, and create a synergistic effect at the metal-semiconductor interface. In recent years, there has been a rise in the number of publications related to the M-S effect on electrocatalysis. In this review, we comprehensively summarize the M-S mechanism and the structural advantages of the M-S heterointerface with various nanoscale featured transition metal nitrides, phosphides, carbides, oxides, hydroxides, chalcogenides, and noble metal composites. Finally, we briefly propose the obstacles, limitations, possibilities, and future directions for M-S heterostructure catalysts in water electrolysis. � 2023 American Chemical Society.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.1021/acsanm.3c02677
dc.identifier.epage16139
dc.identifier.issue18
dc.identifier.scopus2-s2.0-85173131154
dc.identifier.spage16106
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85173131154&doi=10.1021%2facsanm.3c02677&partnerID=40&md5=7141a204ff2fdd36945e729deff3b666
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/33974
dc.identifier.volume6
dc.pagecount33
dc.publisherAmerican Chemical Societyen_US
dc.sourceScopus
dc.sourcetitleACS Applied Nano Materials
dc.subjectElectrochemical Water Splitting
dc.subjectHeterojunction
dc.subjectMetal
dc.subjectMott?Schottky
dc.subjectSemiconductor
dc.subjectCarbides
dc.subjectElectrocatalysis
dc.subjectElectronic structure
dc.subjectInterface states
dc.subjectNanotechnology
dc.subjectPhosphorus compounds
dc.subjectPrecious metals
dc.subjectActive site
dc.subjectElectrochemical water splitting
dc.subjectElectrochemicals
dc.subjectElectronic.structure
dc.subjectMott-Schottky
dc.subjectNanoscale catalysts
dc.subjectSchottky effect
dc.subjectStructural modifications
dc.subjectWater splitting
dc.subject]+ catalyst
dc.subjectHeterojunctions
dc.titleReview of Mott-Schottky-Based Nanoscale Catalysts for Electrochemical Water Splittingen_US
dc.typeReviewen_US
dspace.entity.typePublication
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