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Synthesis and study of mixed ligand-metal complexes of 1, 3, 7-trimethylxanthine and 1, 3-dimethyl-7H-purine-2, 6-dione with some other ligands

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dc.citedby6
dc.contributor.authorShaker S.A.en_US
dc.contributor.authorid31767661500en_US
dc.date.accessioned2023-12-29T07:49:32Z
dc.date.available2023-12-29T07:49:32Z
dc.date.issued2011
dc.description.abstractThis work presents synthesis and study of a new mixed ligand metal complexes of 1,3,7-trimethylxanthine and 1,3-dimethyl-7H-purine-2,6-dione with some other ligands like SCN and OCN ions to give the general formula [M(Tx) 2(Tp)2XY] where M=Co(II), Ni(II), Cu(II), Zn(II) and Cd(II), Tx=1,3,7-trimethylxanthine, Tp= 1,3-dimethyl-7H-purine-2,6-dione, X= SCN and Y=OCN. The resulting products were found to be solid which have been characterized using UV-Visible and infrared spectroscopy. Elemental analyses were performed using C, H, N analysis and atomic absorption techniques. The magnetic susceptibility and the conductivity were also measured. The present results suggest that the 1,3,7-trimethylxanthine and 1,3-dimethyl-7H-purine-2,6- dione were coordinated with metal ions through the nitrogen atom. Thiocyanate ion was coordinated with metal ions through the sulfur atom and the cyanate ion was coordinated with metal ions through the oxygen atom.en_US
dc.description.natureFinalen_US
dc.identifier.doi10.1155/2011/943103
dc.identifier.epage158
dc.identifier.issue1
dc.identifier.scopus2-s2.0-79951645945
dc.identifier.spage153
dc.identifier.urihttps://www.scopus.com/inward/record.uri?eid=2-s2.0-79951645945&doi=10.1155%2f2011%2f943103&partnerID=40&md5=f6f905efe3aebd24465ec5269b2b2486
dc.identifier.urihttps://irepository.uniten.edu.my/handle/123456789/30564
dc.identifier.volume8
dc.pagecount5
dc.publisherHindawi Limiteden_US
dc.relation.ispartofAll Open Access; Gold Open Access
dc.sourceScopus
dc.sourcetitleE-Journal of Chemistry
dc.subject1,3,7-trimethylxanthine complexes
dc.subject1,3-dimethyl-7H-purine-2,6-dione complexes
dc.subjectCyanate complexes
dc.subjectMixed ligand complexes
dc.subjectThiocyanate complexes
dc.titleSynthesis and study of mixed ligand-metal complexes of 1, 3, 7-trimethylxanthine and 1, 3-dimethyl-7H-purine-2, 6-dione with some other ligandsen_US
dc.typeArticleen_US
dspace.entity.typePublication
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